High-Precision Catalysts: Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes
| Autor: | Mark Kuil, T. Soltner, Joost N. H. Reek, P.W.N.M. van Leeuwen |
|---|---|
| Přispěvatelé: | Homogeneous and Supramolecular Catalysis (HIMS, FNWI) |
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Aldehydes Molecular Structure Alkene High selectivity chemistry.chemical_element Regioselectivity General Chemistry Alkenes Biochemistry Catalysis Rhodium chemistry.chemical_compound Colloid and Surface Chemistry Isomerism chemistry Organic chemistry Octene Hydroformylation |
| Zdroj: | Journal of the American Chemical Society, 128(35), 11344-11345. American Chemical Society |
| ISSN: | 0002-7863 |
| Popis: | We report the formation of high-precision catalysts using encapsulated rhodium complexes. In the current example, the encapsulated rhodium catalyst shows unprecedented high selectivity in the rhodium-catalyzed hydroformylation of internal alkenes, forming predominantly one of the branched aldehydes. This catalyst system is the first example that is able to discriminate between carbon atoms C3 and C4 in trans-3-octene. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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