Molecular conductance of double-stranded DNA evaluated by electrochemical capacitance spectroscopy
| Autor: | María Isabel Pividori, Susana Liébana, Paulo Roberto Bueno, Luís Moreira Gonçalves, Willian C. Ribeiro |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
Analytical chemistry Nanowire Nanotechnology 02 engineering and technology Electric Capacitance 010402 general chemistry 01 natural sciences Electron Transport chemistry.chemical_compound Electrical resistivity and conductivity Molecular conductance General Materials Science Spectroscopy Nanowires Electric Conductivity Conductance DNA 021001 nanoscience & nanotechnology Electron transport chain 0104 chemical sciences Models Chemical chemistry Dielectric Spectroscopy 0210 nano-technology |
| Zdroj: | Nanoscale. 8:8931-8938 |
| ISSN: | 2040-3372 2040-3364 |
| DOI: | 10.1039/c6nr01076h |
| Popis: | Conductance was measured in two different double stranded DNA (both with 20 bases), the more conducting poly(dG)-poly(dC) (ds-DNAc) and the less conducting poly(dA)-poly(dT) (ds-DNAi), by means of Electrochemical Capacitance Spectroscopy (ECS). The use of the ECS approach, exemplified herein with DNA nanowires, is equally a suitable and time-dependent advantageous alternative for conductance measurement of molecular systems, additionally allowing better understanding of the alignment existing between molecular scale conductance and electron transfer rate. |
| Databáze: | OpenAIRE |
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