Selectivity in the oxidation of limonene by amphiphilized metalloporphyrins in micellar media
| Autor: | Giovanna Mancini, Federica Marotti, Alessandra Pastorini, Stefano Borocci and, Donato Monti and |
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| Jazyk: | angličtina |
| Rok vydání: | 2001 |
| Předmět: |
chemistry.chemical_classification
Limonene Double bond Chemistry chemistry.chemical_element Regioselectivity Surfaces and Interfaces Manganese Condensed Matter Physics Catalysis chemistry.chemical_compound Electrochemistry Organic chemistry General Materials Science Stereoselectivity Enantiomer Selectivity Spectroscopy |
| Popis: | The weak interactions responsible for the aggregation and organization of micellar aggregates have been shown to control the regioselectivity of the epoxidation of limonene catalyzed by manganese porphyrins toward the endo double bond. The same reaction carried out in the presence of aggregates formed by sodium N-dodecanoyl-l-prolinate has shown the same regioselectivity, a selectivity toward the R enantiomer of limonene and a slight but significative stereoselectivity due to the organization of the molecular aggregates. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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