Acyloxylation of 1,4-Dioxanes and 1,4-Dithianes Catalyzed by a Copper–Iron Mixed Oxide

Autor:	María J. Ortega, F. Javier Moreno-Dorado, Francisco M. Guerra, Guillermo M. Massanet, Hilario Vidal, Ruben Marin‐Barrios, José M. Gatica, Ana Leticia García-Cabeza
Přispěvatelé:	Química Orgánica
Rok vydání:	2015
Předmět:	Chemistry Acyloxylation Organic Chemistry Heteroatom chemistry.chemical_element Mixed oxide Organic chemistry Homogeneous catalysis Heterogeneous catalysis Copper Catalysis
Zdroj:	Journal of Organic Chemistry 2015, 80, 6814−6821
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.5b01043
Popis:	The use of a copper−iron mixed oxide as a heterogeneous catalyst for the efficient synthesis of α-acyloxy-1,4-dioxanes and 1,4-dithianes employing t-butyl peroxyesters is reported. The preparation and characterization of the catalyst are described. The effect of the heteroatoms and a plausible mechanism are discussed. The method is operationally simple and involves low-cost starting materials affording products in good to excellent yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2e90542ebc67fd488c73672eab0687ff https://doi.org/10.1021/acs.joc.5b01043 Zobrazit plný text záznamu