Ring-Opening of Donor–Acceptor Cyclopropanes by Boronic Acids and Potassium Organotrifluoroborates under Transition-Metal-Free Conditions
| Autor: | Aurelio G. Csaky, Víctor Ortega |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Potassium Aryl Organic Chemistry chemistry.chemical_element 010402 general chemistry Ring (chemistry) 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Transition metal Polymer chemistry Trifluoroacetic acid Organic chemistry Donor acceptor Vicinal Boron trifluoride |
| Zdroj: | The Journal of Organic Chemistry. 81:3917-3923 |
| ISSN: | 1520-6904 0022-3263 |
| DOI: | 10.1021/acs.joc.6b00320 |
| Popis: | The ring-opening of cyclopropane-1,1-dicarboxylates with vicinal donor aryl groups by boronic acids and potassium organotrifluoroborates under metal-free conditions has been developed. The reaction utilizes trifluoroacetic acid or boron trifluoride as promoters. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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