Total Synthesis of (+)-Polyoxamic Acid via Visible-Light-Mediated Photocatalytic β-Scission and 1,5-Hydrogen Atom Transfer of Glucose Derivative

Autor:	Hiroaki Ohno, Shinya Oishi, Takashi Miyagawa, Shinsuke Inuki, Takuro Matsuoka
Rok vydání:	2020
Předmět:	chemistry.chemical_compound Chemistry Organic Chemistry Atom Photocatalysis Total synthesis Hydrogen atom Photochemistry Polyoxamic acid Bond cleavage Derivative (chemistry) Visible spectrum
Zdroj:	The Journal of organic chemistry. 85(12)
ISSN:	1520-6904
Popis:	A total synthesis of polyoxamic acid has been achieved. The key feature of the synthetic route is a visible-light-mediated β-scission and carbon-to-carbon 1,5-hydrogen atom transfer (1,5-HAT) to provide the functionalized alditol under mild conditions. This type of carbon-to-carbon 1,5-HAT initiated by C(sp
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2e67ebf3714065397b49ac77d5087506 https://pubmed.ncbi.nlm.nih.gov/32425047 Zobrazit plný text záznamu