Analysis of silica hydride and surface hydrosilation reactions by solid-state NMR in the preparation of p-chlorobenzamide bonded silica phase

Autor:	G. H. Müller, Liam Healy, Klaus Albert, Matthias Pursch, Jeremy D. Glennon, B. Lynch
Rok vydání:	2003
Předmět:	Solid-state nuclear magnetic resonance Chemistry Hydride Phase (matter) Polymer chemistry Analytical chemistry Infrared spectroscopy Nuclear magnetic resonance spectroscopy Spectroscopy Biochemistry Analytical Chemistry Catalysis Hydrophobic silica
Zdroj:	Analytical and bioanalytical chemistry. 377(6)
ISSN:	1618-2642
Popis:	29Si and (13)C CP-MAS NMR spectroscopy was used to follow the conversion of native silica to a p-chlorobenzamide bonded silica material. The benzamide bonded phase was prepared via a hydrosilation reaction of a hydride silica intermediate with p-chloro- N-allylbenzamide. Solid-state NMR was used to show the disappearance of reactive surface hydride species (M(H)) and to identify newly formed bonded chemical species on the silica surface. DRIFT spectroscopy, elemental analysis, and specific surface-area determinations (BET) of the prepared phases are also reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2e1b01fee1e21ff7cc23853ab9fca3c2 https://pubmed.ncbi.nlm.nih.gov/14556045 Zobrazit plný text záznamu Plný text ve formátu PDF