Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site
| Autor: | Frédéric Gloaguen, Jean Talarmin, François Y. Pétillon, Sondes Lounissi, Jean-François Capon, Fatma Matoussi, Philippe Schollhammer |
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| Přispěvatelé: | Chemical and Biological Engineering Department, Institut National des Sciences Appliquées et de Technologie [Tunis] (INSAT), Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA), Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Models
Molecular Proton Stereochemistry Phosphines [CHIM.INOR]Chemical Sciences/Inorganic chemistry 010402 general chemistry Electrochemistry 01 natural sciences Medicinal chemistry Ferric Compounds Catalysis Electron Transport Hydrogenase Catalytic Domain Materials Chemistry [CHIM.COOR]Chemical Sciences/Coordination chemistry Sulfhydryl Compounds Diiron dithiolate biology 010405 organic chemistry Chemistry Metals and Alloys Active site General Chemistry Electron transport chain 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ceramics and Composites biology.protein |
| Zdroj: | Chemical Communications Chemical Communications, Royal Society of Chemistry, 2011, 47 (3), pp.878-880. ⟨10.1039/C0CC03295F⟩ |
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/C0CC03295F⟩ |
| Popis: | A new dissymmetrically disubstituted diiron dithiolate species, [Fe(2)(CO)(4)(κ(2)-P(Ph)(2)N(Ph)(2))(μ-pdt)] (pdt = S(CH(2))(3)S), was prepared by using a flexible cyclic base-containing diphosphine, 1,3,5,7-tetraphenyl 1,5-diaza-3,7-diphosphacyclooctane (P(Ph)(2)N(Ph)(2) = {PhPCH(2)NPh}(2)). Preliminary investigations of proton and electron transfers on the diiron system have been done. |
| Databáze: | OpenAIRE |
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