Tetraorganoindates as Nucleophilic Coupling Partners in Pd-Catalyzed Cross-Coupling Reactions

Autor:	Phil Ho Lee, Sung Wook Lee, Dong Seomoon
Rok vydání:	2003
Předmět:	Aryl Organic Chemistry General Medicine Biochemistry Medicinal chemistry Coupling reaction Catalysis Coupling (electronics) Indium Trichloride chemistry.chemical_compound chemistry Nucleophile Atom economy Electrophile Organic chemistry Physical and Theoretical Chemistry
Zdroj:	Organic Letters. 5:4963-4966
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol035883o
Popis:	In situ-generated tetraorganoindate complexes from the reaction of 1 equiv of indium trichloride with 4 equiv of appropriate organometallics are efficient nucleophiles in Pd-catalyzed cross-coupling reactions. In this novel reaction tetraorganoindates containing methyl, 1 degree- and 2 degree-alkyl, vinyl, alkynyl, and aryl groups transfer the four organic groups to a variety of electrophiles with high atom efficiency. [reaction: see text]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2deff7a9d8785e9f997cca80480d207d https://doi.org/10.1021/ol035883o Zobrazit plný text záznamu