'CLICKable' azide-functionalized phosphonates for the surface-modification of molecular and solid-state metal oxides
| Autor: | Montaha Anjass, Stefanie Schönweiz, Carsten Streb, Sven Rau, Markus Braumüller, S Knoll |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Chemistry Solid-state Oxide 010402 general chemistry 01 natural sciences Phosphonate 0104 chemical sciences Inorganic Chemistry Covalent functionalization Metal chemistry.chemical_compound visual_art Polymer chemistry visual_art.visual_art_medium Surface modification Organic chemistry Azide Bifunctional |
| Zdroj: | Dalton transactions (Cambridge, England : 2003). 45(41) |
| ISSN: | 1477-9234 |
| Popis: | The covalent functionalization of metal oxide surfaces with organic ligands gives unique organic-inorganic hybrids. Here we report a bifunctional organic tether combining a phosphonate for metal oxide anchoring with an organic azide for attachment of organic groups. Stable binding of the tether to molecular and solid-state metal oxides is demonstrated and the subsequent "CLICKability" of the TiO2-anchored tether is shown. The phosphonate-azide reported could in future allow the general linkage of functional organic groups to metal oxides. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|