Thiol-Ene-Clickable And Emissive Carbazole-Based Polymer Networks With Tunable Colors
| Autor: | Özlem Usluer, Ceylan Doyranli, Sumeyra Buyukcelebi, Fatma Baycan Koyuncu, Mahmut Kus, Sermet Koyuncu |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Carbazole Band gap General Chemical Engineering 02 engineering and technology General Chemistry Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry Pentaerythritol 0104 chemical sciences chemistry.chemical_compound chemistry Suzuki reaction Polymerization Polymer chemistry Materials Chemistry Click chemistry Environmental Chemistry 0210 nano-technology Ene reaction |
| Popis: | Band gap tuning and processability of organic materials are significant topics for both scientific research and commercial applications. In this study, we synthesized a series of main chain cross-linkable polymers by thiol-ene click chemistry from N-allyl carbazole and different heterocycles via conventional Suzuki coupling polymerization reaction. The emission color of polymers could be successfully tuned from blue to red by attaching different benzazole-acceptor moieties to the carbazole donor unit. We also investigated the effects of cross-linking with respect to the amount of pentaerythritol tetrakis(3-mercaptopropionate) cross-linker on the optical, electrochemical, and surface morphological properties of the polymer films. The results showed that these polymers can be used as emissive active layers in solution-processable multilayer organic light-emitting diodes. (C) 2016 Published by Elsevier B.V. |
| Databáze: | OpenAIRE |
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