A crystalline porous coordination polymer decorated with nitroxyl radicals catalyzes aerobic oxidation of alcohols

Autor:	Maw Lin Foo, Susumu Kitagawa, Iku Tanaka, Yasujiro Murata, Atsushi Wakamiya, Hyung Joon Jeon, Prakash Kanoo, Ryotaro Matsuda, Liangchun Li, Hiroshi Sato
Rok vydání:	2014
Předmět:	Nitroxide mediated radical polymerization Coordination polymer Ligand Nitroxyl General Chemistry Isoindoline Photochemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Alcohol oxidation Porosity
Zdroj:	Journal of the American Chemical Society. 136(21)
ISSN:	1520-5126
Popis:	A porous coordination polymer (PCP) has been synthesized employing an organic ligand in which a stable free radical, isoindoline nitroxide, is incorporated. The crystalline PCP possesses one-dimensional channels decorated with the nitroxyl catalytic sites. When O2 gas or air was used as the oxidant, this PCP was verified to be an efficient, recyclable, and widely applicable catalyst for selective oxidation of various alcohols to the corresponding aldehydes or ketones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2da3720fb3705f678b15761e1da76eb5 https://pubmed.ncbi.nlm.nih.gov/24816302 Zobrazit plný text záznamu