p -Type and n -type conductometric behaviors of octachloro-metallophthalocyanine-based heterojunctions, the key role of the metal
| Autor: | Rita Meunier-Prest, Marcel Bouvet, Tahirou Coulibaly, Seydou Ouedraogo, Mabinty Bayo-Bangoura |
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| Přispěvatelé: | Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon] (ICMUB), Centre National de la Recherche Scientifique (CNRS)-Université de Bourgogne (UB)-Institut de Chimie du CNRS (INC), Université Joseph Ki-Zerbo [Ouagadougou] (UJZK), Laboratoire de Chimie Inorganique et Matériaux Moléculaires (CIM2), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre d'Études et de Recherches sur le Développement International (CERDI), Université d'Auvergne - Clermont-Ferrand I (UdA)-Centre National de la Recherche Scientifique (CNRS), Université de Bourgogne (UB)-Centre National de la Recherche Scientifique (CNRS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Heterojunction
02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Ion Metal Ammonia chemistry.chemical_compound chemistry Molecular semiconductor visual_art visual_art.visual_art_medium Physical chemistry [CHIM]Chemical Sciences 0210 nano-technology ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Journal of Porphyrins and Phthalocyanines Journal of Porphyrins and Phthalocyanines, World Scientific Publishing, 2020, 24 (05n07), pp.750-757. ⟨10.1142/s1088424619501669⟩ |
| ISSN: | 1088-4246 1099-1409 |
| Popis: | In the present work, we determined the electrical properties of octachlorinated metallophthalocyanines with Co(II) and Cu(II) ions as metal centers. We engaged them in heterojunctions, with lutetium bisphthalocyanine as a partner. Surprisingly, cobalt and copper complexes show opposite behaviors, the first being an [Formula: see text]-type material whereas the latter is a [Formula: see text]-type material, as deduced from the response of the heterojunctions towards ammonia; showing the unusual key role played by the metal center. While the LuPc[Formula: see text]/Cu(Cl[Formula: see text]Pc) complex exhibits a negative response to ammonia, the LuPc[Formula: see text]/Co(Cl[Formula: see text]Pc) complex exhibits a positive response to ammonia, with a sensitivity of 1.47% ppm[Formula: see text] at concentrations lower than 10 ppm and a limit of detection of 250 ppb. All the devices operate at room temperature and in real atmosphere. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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