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The reaction of the Pt complexes cis-[Pt(CH3)2{R2P(Ind)}2] (Ind=2-(3-methyl)indolyl, R=Ph (1 a), 4-FC6H4 (1 b), 4-CF3C6H4 (1 c)) with HF afforded the fluorido complexes trans-[Pt(F(HF)2)(CH3){R2P(Ind)}2] 2 a–c, which can be converted into trans-[Pt(F)(CH3){R2P(Ind)}2] (3 a–c) by treatment with CsF. Addition of 3-hexyne to 2 a–c gave alkyne complexes trans-[Pt(C,C-η2-C2H5C≡CC2H5)(CH3){R2P(Ind)}2{F(HF)2}] (4 a–c) at which a fluoride is stabilised as polyfluoride in the coordination sphere by hydrogen bonding to the indolyl-substituted phosphine ligands. Subsequent heating of a solution of 4 a in the presence of PVPHF led to fluoroalkene formation. Selective catalytic hydrofluorination of alkynes to yield (Z)-fluoroalkenes were developed. The ability of hydrogen bonding to polyfluoride favours the fluorination step as demonstrated by studies with complexes bearing no indolyl groups at the phosphine ligands. |
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