Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid
| Autor: | M.M. Bouman, E. W. Meijer, Maurice Maria Johannes Simenon, Edsko Enno Havinga, Anita Pomp |
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| Přispěvatelé: | Macromolecular and Organic Chemistry |
| Rok vydání: | 1994 |
| Předmět: |
chemistry.chemical_classification
Conductive polymer Quantitative Biology::Biomolecules Circular dichroism Dopant High Energy Physics::Lattice Mechanical Engineering Camphorsulfonic acid Doping Metals and Alloys Sulfonic acid Condensed Matter Physics Photochemistry Electronic Optical and Magnetic Materials Condensed Matter::Materials Science chemistry.chemical_compound chemistry Mechanics of Materials Condensed Matter::Superconductivity Polyaniline Materials Chemistry Organic chemistry Chirality (chemistry) |
| Zdroj: | Synthetic Metals, 66(1), 93-97. Elsevier |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/0379-6779(94)90168-6 |
| Popis: | A large induced circular dichroism is found in the conduction band of polyaniline doped with optically active camphorsulfonic acid. In films obtained by spin-coating from a meta -cresol solution, the chiral dopant induces chirality within the main chain of polyaniline. No other combinations of achiral conducting polymers and chiral dopants have been found that show induced optical activity in their conduction band. |
| Databáze: | OpenAIRE |
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