Studies on thermal decomposition mechanism of CL-20 by pyrolysis gas chromatography-mass spectrometry (Py-GC/MS)
| Autor: | B.R. Gandhe, Arun K. Sikder, Girish M. Gore, Nilesh H. Naik |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
Bridged-Ring Compounds
Chemical ionization Environmental Engineering Hot Temperature Nitrosamines Chemistry Health Toxicology and Mutagenesis Thermal decomposition Analytical chemistry Mass chromatogram Mass spectrometry Chromatography Ion Exchange Nitro Compounds Pollution Gas Chromatography-Mass Spectrometry Mass Spectrometry Pyrolysis–gas chromatography–mass spectrometry Mass spectrum Environmental Chemistry Gas chromatography Waste Management and Disposal Electron ionization Chromatography High Pressure Liquid |
| Zdroj: | Journal of hazardous materials. 159(2-3) |
| ISSN: | 0304-3894 |
| Popis: | The thermal decomposition study of CL-20 (hexanitrohexaazaisowurtzitane) using pyrolysis GC/MS was carried out mainly by electron impact (EI) mode. Chemical ionization (CI) mode was used for further confirmation of identified species. Mass spectrum of CL-20 decomposition products predominantly revealed fragments with m / z 81 and 96 corresponding to C 4 H 5 N 2 + and C 4 H 4 N 2 O + ions, respectively. The total ion chromatogram (TIC) of CL-20 pyrolysis shows peak within first 2 min due to the presence of low molecular weight gases. Peaks corresponding to several other products were also observed including the atmospheric gases. Cyanogen formation (C 2 N 2 , m / z 52) observed to be enriched at the scan number 300–500. The low molecular mass range decomposition products formed by cleavage of C–N ring structure were found in majority. Additional structural information was sought by employing chemical ionization mode. The data generated during this study was instrumented in determining decomposition pathways of CL-20. |
| Databáze: | OpenAIRE |
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