6,6′-Bisperfluoroalkylated BINOLs Promoted Asymmetric Allylation of Aldehydes
Autor: | Wei-xing Yin, Gang Zhao, Yue-yan Yin, Zhan-shan Qian |
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Rok vydání: | 2003 |
Předmět: | |
Zdroj: | ChemInform. 34 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.200330034 |
Popis: | 6,6′-Bis(1H, 1H, 2H, 2H-perfluorooctyl)-1, 1′-bi-2-naphthol (Rf6-BINOL) and 6,6′-bis(1H, 1H, 2H, 2H-perfluorodecyl)-1,1′-bi-2-naphthol (Rf8-BINOL) were used in allylation of aldehydes in fluorous biphase system. Good enantioselectivity was obtained and the ligands could be recovered by continuos liquid–liquid extraction. |
Databáze: | OpenAIRE |
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