6,6′-Bisperfluoroalkylated BINOLs Promoted Asymmetric Allylation of Aldehydes

Autor: Wei-xing Yin, Gang Zhao, Yue-yan Yin, Zhan-shan Qian
Rok vydání: 2003
Předmět:
Zdroj: ChemInform. 34
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200330034
Popis: 6,6′-Bis(1H, 1H, 2H, 2H-perfluorooctyl)-1, 1′-bi-2-naphthol (Rf6-BINOL) and 6,6′-bis(1H, 1H, 2H, 2H-perfluorodecyl)-1,1′-bi-2-naphthol (Rf8-BINOL) were used in allylation of aldehydes in fluorous biphase system. Good enantioselectivity was obtained and the ligands could be recovered by continuos liquid–liquid extraction.
Databáze: OpenAIRE