Heterogeneous Clusters of Phthalocyanine and Water Prepared and Probed in Superfluid Helium Nanodroplets
| Autor: | E.-M. Lottner, Lars Christiansen, Denis Usvyat, F. Schlaghaufer, Bretislav Friedrich, Th. Mullan, Martin Schütz, Henrik Stapelfeldt, Johannes Fischer, Mallikarjun Karra, Alkwin Slenczka |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Coalescence (physics)
010304 chemical physics chemistry.chemical_element 010402 general chemistry 01 natural sciences Electron spectroscopy Spectral line 0104 chemical sciences chemistry Chemical physics Metastability 0103 physical sciences Cluster (physics) Physics::Atomic and Molecular Clusters Molecule Physics::Chemical Physics Physical and Theoretical Chemistry Superfluid helium-4 Helium |
| Zdroj: | Fischer, J, Schlaghaufer, F, Lottner, E M, Slenczka, A, Christiansen, L, Stapelfeldt, H, Karra, M, Friedrich, B, Mullan, T, Schütz, M & Usvyat, D 2019, ' Heterogeneous Clusters of Phthalocyanine and Water Prepared and Probed in Superfluid Helium Nanodroplets ', Journal of Physical Chemistry A, vol. 123, no. 46, pp. 10057-10064 . https://doi.org/10.1021/acs.jpca.9b07302 The Journal of Physical Chemistry A |
| DOI: | 10.1021/acs.jpca.9b07302 |
| Popis: | Superfluid helium nanodroplets comprised of thousands to millions of helium atoms can serve as a reactor for the synthesis of heterogeneous molecular clusters at cryogenic conditions. The cluster synthesis occurs via consecutive pick-up of the cluster building blocks by the helium droplet and their subsequent coalescence within the droplet. The effective collision cross section of the building blocks is determined by the helium droplet size and thus exceeds by orders of magnitude that of a reactive collision in the gas phase. Moreover, the cryogenic helium environment (at 0.38 K) as a host promotes the formation of metastable cluster configurations. The question arises as to the extent of the actual involvement of the helium environment in the cluster formation. The present study deals with clusters of single phthalocyanine (Pc) molecules with single water molecules. A large fluorophore such as Pc offers several sites where the water molecule can attach. The resulting isomeric variants of the Pc-H2O complex can be selectively identified by electronic spectroscopy. We compare the experimental electronic spectra of the Pc-H2O complex generated in superfluid helium nanodroplets with the results of quantum-chemical calculations on the same cluster but under gas-phase conditions. The number of isomeric variants observed in the helium droplet experiment comes out the same as that obtained from our gas-phase calculations. |
| Databáze: | OpenAIRE |
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