Structure-Directing Role of Phosphonate in the Synthesis of High-Nuclearity Silver(I) Sulfide-Ethynide-Thiolate Clusters
| Autor: | Yunpeng Xie, Han Cui, Thomas C. W. Mak, Guang-Xiong Duan, Xing Lu, Jun-Ling Jin |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry Silver sulfide Inorganic chemistry 010402 general chemistry 01 natural sciences Phosphonate 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Cluster (physics) Physical and Theoretical Chemistry |
| Zdroj: | Inorganic Chemistry. 56:10412-10417 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Phosphonate ligands as structure-directing components have been employed to construct four new high-nuclearity silver(I) sulfide-ethynide-thiolate clusters, in which silver(I) aggregates tBuC≡C⊃Ag3, tBuC≡C⊃Ag4, and 2tBuC≡C⊃Ag7 are bridged by tBuS– ligands to engender respective silver(I) ethynide-thiolate clusters functioning as integral shell components, which are supported by phosphonate ligands. In each silver(I) sulfide-ethynide-thiolate cluster, a different encapsulated silver sulfide cluster serves as a core template. |
| Databáze: | OpenAIRE |
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