New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
| Autor: | İbrahim Demirel, Nurcan Acar, Elif Bulat, Ertuğrul Gazi Sağlam |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Chemistry Inorganic and Nuclear Chloroform Metal salts Aryl Alcohol Kimya İnorganik ve Nükleer General Chemistry Medicinal chemistry lcsh:Chemistry chemistry.chemical_compound symbols.namesake phosphonodthioic acid chemistry lcsh:QD1-999 symbols dithiophosphonic acid Fourier transform infrared spectroscopy Raman spectroscopy Stoichiometry Alkyl Dithiophosphonic Acid Phosphonodthioic Acid Dithiophosphonate Complexes dithiophosphonate complexes |
| Zdroj: | Journal of the Turkish Chemical Society, Section A: Chemistry, Vol 7, Iss 1, Pp 49-64 (2020) Volume: 7, Issue: 1 49-64 Journal of the Turkish Chemical Society Section A: Chemistry |
| ISSN: | 2149-0120 |
| Popis: | New Cd(II) and Hg(II) complexes of previously known five dithiophosphonic acids ((p-MeO-C6H4)PS(SH)(OR), HLn, (n= 1-5); R= 3-pentyl-, HL1; R=1-phenyl-1-propyl-, HL2; R= 4-tert-butyl benzyl-, HL3; R= diphenylmethyl-, HL4; R= 4-tert- butyl cyclohexyl-, HL5) were prepared and characterized. To do this, the dithiophosphonic acids involved were treated with stoichiometric amount of the corresponding metal salts in methyl alcohol. The complexes came of as powdery crystals and were recrystallized from chloroform. The pure complexes were characterized by using elemental analyses as well as mas-(ESI), FTIR-, Raman-, NMR- (1H, 13C, 31P) spectroscopies. |
| Databáze: | OpenAIRE |
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