Diamine-mediated degradative dimerisation of Morita–Baylis–Hillman ketones

Autor: Srinivasan Easwar, Ajit Kumar Jha, Anju Kumari
Rok vydání: 2020
Předmět:
Zdroj: Chemical Communications. 56:2949-2952
ISSN: 1364-548X
1359-7345
Popis: A degradative dimerisation of Morita-Baylis-Hillman ketones was observed in the presence of a primary diamine. The reaction proceeded swiftly to produce methylene-bridged 1,3-dicarbonyl compounds. A brief mechanistic investigation alluded to a retro-Mannich reaction as the key step of the transformation.
Databáze: OpenAIRE