Diamine-mediated degradative dimerisation of Morita–Baylis–Hillman ketones
Autor: | Srinivasan Easwar, Ajit Kumar Jha, Anju Kumari |
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Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Chemical Communications. 56:2949-2952 |
ISSN: | 1364-548X 1359-7345 |
Popis: | A degradative dimerisation of Morita-Baylis-Hillman ketones was observed in the presence of a primary diamine. The reaction proceeded swiftly to produce methylene-bridged 1,3-dicarbonyl compounds. A brief mechanistic investigation alluded to a retro-Mannich reaction as the key step of the transformation. |
Databáze: | OpenAIRE |
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