Electron-Transfer-Induced Self-Assembly of a Molecular Tweezer Platform

Autor:	Rajendra Rathore, Saber Mirzaei, Khushabu Thakur, Denan Wang
Rok vydání:	2020
Předmět:	010405 organic chemistry Dimer Radical Organic Chemistry General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Electron transfer Delocalized electron chemistry Tweezers Titration Self-assembly Conformational isomerism
Zdroj:	Chemistry (Weinheim an der Bergstrasse, Germany). 26(62)
ISSN:	1521-3765
Popis:	The design and synthesis of a new molecular tweezer (T-tmp) with electron-rich pincers are reported. The stable monocationic radicals and self-assembled dimeric radicals of this molecular tweezer platform were prepared by chemical oxidative titration. With the aid of DFT calculations, it was found that the dimeric radicals with syn-syn-syn conformer has the most stable structure, with the hole primarily delocalized between parallel stacked pyrenyl groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2c640b181122fbcac1d28ee862cc320b https://pubmed.ncbi.nlm.nih.gov/32608146 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.