Organocopper(III) Phenanthriporphyrin—Exocyclic Transformations
| Autor: | Agata Białońska, Lechosław Latos-Grażyński, Bartosz Szyszko, Kamil Kupietz, Michał J. Białek |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry chemistry.chemical_element Protonation 010402 general chemistry 01 natural sciences Medicinal chemistry Borylation Copper 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Oxygen atom Oxidizing agent Methanol Physical and Theoretical Chemistry Boron Carbon |
| Zdroj: | Inorganic Chemistry. 58:1451-1461 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.8b02997 |
| Popis: | 5,6-Dimethoxyphenanthriporphyrin 1 and 5,6-dioxophenanthriporphyrin 2 act as suitable organometallic ligands for copper(III), adopting trianionic [CCNN] coordination cores. Under oxidizing conditions, in the presence of methanol, copper(III) phenanthriporphyrin 1-Cu undergoes transformation to copper(III) phenanthriporphodimethene with methoxy substituents attached to two trans meso positions. Addition of acids to 1-Cu yields two isomeric copper(III) isophenanthriporphyrins protonated on one of the meso carbon atoms. Protonation of copper(III) 5,6-dioxophenanthriporphyrin 2-Cu yields the aromatic diprotonated complex 2-Cu-H22+. In the presence of HBF4 2-Cu undergoes borylation at the carbonyl oxygen atoms, forming an aromatic exocyclic boron(III) complex. |
| Databáze: | OpenAIRE |
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