Strategies and mechanisms of metal-ligand cooperativity in first-row transition metal complex catalysts
| Autor: | Matthew R. Elsby, R. Tom Baker |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Chemistry Ligand Cooperativity Homogeneous catalysis General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis Metal chemistry.chemical_compound Transition metal visual_art visual_art.visual_art_medium Lewis acids and bases Bifunctional |
| Zdroj: | Chemical Society reviews. 49(24) |
| ISSN: | 1460-4744 |
| Popis: | The use of metal-ligand cooperation (MLC) by transition metal bifunctional catalysts has emerged at the forefront of homogeneous catalysis science. Specially designed ligands can serve a Lewis base or Lewis acid function, as an aromatization/dearomatization shuttle, or as an electron reservoir with reversible redox activity. This review encapsulates advances that have been made in this field over the last ten years, focusing exclusively on first-row transition metals, and highlighting significant contributions to mechanistic understanding. |
| Databáze: | OpenAIRE |
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