Fabrication of CDs hybrid MIL-68(In) derived In2O3In2S3 hollow tubular heterojunction and their exceptional self-powered PEC aptasensing properties for ampicillin detecting
| Autor: | Xiang Ren, Tao Yan, Jinkai Li, Huangxian Ju, Liangguo Yan, Qin Wei, Yixuan Feng, Meng Sun, Yizhong Lu |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Working electrode
Materials science MIL-68(In)-derived Aptamer 02 engineering and technology 010402 general chemistry 01 natural sciences Hollow tubes Specific surface area Self-powered Materials of engineering and construction. Mechanics of materials Detection limit Photocurrent business.industry Photoelectrochemical aptasensor Metals and Alloys Heterojunction 021001 nanoscience & nanotechnology 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Linear range Electrode TA401-492 Optoelectronics Ampicillin 0210 nano-technology business |
| Zdroj: | Journal of Materiomics, Vol 7, Iss 4, Pp 721-727 (2021) |
| ISSN: | 2352-8478 |
| Popis: | A visible-light-driven self-powered photoelectrochemical (PEC) aptasensor was developed for ampicillin (AMP) detecting based on carbon dots (CDs) hybrid MIL-68(In)-derived In2O3 In2S3 hollow tubular heterojunction (CDs/In2O3 In2S3). In2S3 nanosheets uniformly grew in-situ on the surface of In2O3 hollow tubes, forming a close contact heterogeneous interface, which significantly promoted the transfer and separation of photo-generated carriers, and provided a large specific surface area and rich active sites for the PEC aptasensing platform. Furthermore, the CDs/In2O3 In2S3/ITO electrode, which was obtained by dipping assembly, showed remarkable and stable photoelectric signals at zero-bias under visible light irradiation. The amino-functionalized AMP aptamer was fixed on the working electrode as a biological recognition element, and the concentration of AMP was determined by observing the change in photocurrent intensity caused by the specific capture of AMP molecules in solution. Under optimized conditions, the developed PEC aptasensor displayed a relatively wide linear range from 0.001 ng mL−1 to 300 ng mL−1, as well as a low detection limit (LOD) of 0.06 pg mL−1. Besides, the novel self-powered PEC AMP-aptasensor exhibited excellent reproducibility, good stability and selectivity, which open a potential avenue for antibiotic residues detection in environmental media. |
| Databáze: | OpenAIRE |
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