Controlled design of Na-P1 zeolite/ porous carbon composites from coal gasification fine slag for high-performance adsorbent

Autor: Rui Shu, Qixia Qiao, Feiqiang Guo, Kaiming Dong, Sha Liu, Liya Xu, Yonghui Bai, Nan Zhou
Rok vydání: 2022
Předmět:
Zdroj: Environmental research. 217
ISSN: 1096-0953
Popis: Low-cost and concentrated industrial wastes have been recognized as a sustainable resource for preparation of new functional materials. Here, a new method was designed for the synthesis of porous composites containing high-purity Na-P1 zeolite and porous carbon from waste coal gasification fine slag (CGFS), which was treated first by acid leaching to controllably remove metal impurities and adjust Si/Al ratio, followed by NaOH fusion and hydrothermal treatment. By leaching with 1.0 mol/L HCl solution, the Si/Al ratio of the raw CGFS increased to 5.7, and the obtained CZ-1.0 consisted of high-purity Na-P1 zeolite with a typical cone-shaped flower cluster shape. The residue carbon in CGFS can be further activated to form porous carbon and graphite carbon layers interposed in the zeolite structure. The specific surface area and pore volume of CZ-1.0 reached 153.91 m
Databáze: OpenAIRE