Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7-Fold to 8-Fold Interpenetrated Metal-Organic Frameworks (MOFs)
| Autor: | Gianpiero Gallo, Zhihui Chen, Robert E. Dinnebier, Hong Sheng Quah, Tianxiang Zhang, Menglong Zhu, Anjana Chanthapally, Xiaogang Liu, V.A. Sawant, Jagadese J. Vittal, Geetha Bolla, Kian Ping Loh, Liangliang Liang, Qing-Hua Xu |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Photoluminescence 010405 organic chemistry Oscillator strength Energy conversion efficiency Nonlinear optics Second-harmonic generation General Chemistry General Medicine 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Dipole Chemical physics Molecule Metal-organic framework |
| Zdroj: | Angewandte Chemie (International ed. in English). 59(2) |
| ISSN: | 1521-3773 |
| Popis: | Interpenetration in metal-organic frameworks (MOFs) is an intriguing phenomenon with significant impacts on their properties, and functional applications. Herein, we show that a 7-fold interpenetrated MOF (1) is transformed into an 8-fold interpenetrated MOF by the loss of DMF in a single-crystal-to-single-crystal manner. This is accompanied by a giant enhancement of the second harmonic generation (SHG ca. 125 times) and two-photon photoluminescence (ca. 14 times). The strengthened π-π interaction between the individual diamondoid networks and intensified oscillator strength of the molecules aid the augment of dipole moments and boost the nonlinear optical conversion efficiency. Large positive and negative thermal expansions of 1 occur at 30-150 °C before the loss of DMF. These results offer an avenue to manipulate the NLO properties of MOFs using interpenetration and provide access to tunable single-crystal NLO devices. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text