Synthesis of the Cyclobutanone Core of Solanoeclepin A via Intramolecular Allene Butenolide Photocycloaddition

Autor:	Kees Goubitz, Kimberly K. Larson, Frank S. Jr. Guziec, Jan Fraanje, H. Schenk, Henk Hiemstra, J. Dijkink, Sanne Kuiper, Jan H. van Maarseveen, Bui T. B. Hue
Přispěvatelé:	Synthetic Organic Chemistry (HIMS, FNWI), HIMS Other Research (FNWI)
Rok vydání:	2004
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Double bond chemistry Stereochemistry Intramolecular force Allene Regioselectivity Cyclobutanone General Medicine Bridged compounds Ring (chemistry) Butenolide
Zdroj:	Organic & Biomolecular Chemistry, 24, 4364-4366. Royal Society of Chemistry
ISSN:	1522-2667 0931-7597 1477-0539
Popis:	The compact tricyclic substructure of solanoeclepin A containing the cyclobutanone ring was prepared by using as the key step a highly regioselective intramolecular [2 + 2]-photocycloaddition reaction between one of the π-bonds of an allene and the CC double bond of a butenolide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2af92f5202d638d2febacd34d5f69701 https://doi.org/10.1002/chin.200420029 Zobrazit plný text záznamu Plný text