Novel polyoxometalate–phosphazene aggregates and their use as catalysts for biphasic oxidations with hydrogen peroxide
| Autor: | Rana Yahya, Michael Craven, Elena F. Kozhevnikova, Ivan V. Kozhevnikov, Alexander Steiner, Craig M. Robertson, Ramamoorthy Boomishankar |
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| Rok vydání: | 2013 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Inorganic chemistry Metals and Alloys Mixing (process engineering) Salt (chemistry) General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Polyoxometalate Materials Chemistry Ceramics and Composites Organic chemistry Hydrogen peroxide Phosphazene |
| Zdroj: | Chem. Commun.. 49:349-351 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Polyoxometalate-phosphazene salt aggregates comprising cyclophosphazene cations are highly efficient catalysts for environmentally benign biphasic oxidations with hydrogen peroxide. These catalysts self-assemble in situ simply by mixing commercial Keggin POMs and readily available phosphazenes. |
| Databáze: | OpenAIRE |
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