Three-component synthesis of 1,4-benzothiazines via iodide-catalyzed aerobic C-H sulfuration with elemental sulfur

Autor:	Guo-Jun Deng, Xiaolong Tuo, Huawen Huang, Jingjing Jiang, Zhuquan Fu
Rok vydání:	2020
Předmět:	chemistry.chemical_classification Chemistry Component (thermodynamics) Organic Chemistry Thiazole formation Polymer chemistry Iodide Surface modification chemistry.chemical_element Physical and Theoretical Chemistry Biochemistry Sulfur Catalysis
Zdroj:	Organicbiomolecular chemistry. 18(17)
ISSN:	1477-0539
Popis:	Herein, iodide-catalyzed aerobic synthesis of 1,4-benzothiazines via functionalization of multiple C-H bonds with elemental sulfur is described. Beyond the well-established thiazole formation from elemental sulfur, this method provides the first access to the corresponding six-membered N,S-heterocyclic products via direct functionalization of multiple C-H bonds. Hence, 1,4-benzothiazine products were generated in satisfactory yields with a range of compatible functionalities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2ad114c9151a0c2c39fa7b0b9395a9c4 https://pubmed.ncbi.nlm.nih.gov/32270843 Zobrazit plný text záznamu