The Xanthate Route to Amines, Anilines, and Other Nitrogen Compounds. A Brief Account
| Autor: | Beatrice Quiclet‐Sire, Samir Z. Zard |
|---|---|
| Přispěvatelé: | Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2016 |
| Předmět: |
[CHIM.ORGA]Chemical Sciences/Organic chemistry
010405 organic chemistry Radical Organic Chemistry chemistry.chemical_element Related derivatives 010402 general chemistry 01 natural sciences Nitrogen 0104 chemical sciences chemistry.chemical_compound chemistry β lactams Organic chemistry Amine synthesis Xanthate ComputingMilieux_MISCELLANEOUS |
| Zdroj: | SYNLETT SYNLETT, Georg Thieme Verlag, 2016, 27 (5), pp.680-701. ⟨10.1055/s-0035-1561300⟩ |
| ISSN: | 1437-2096 0936-5214 |
| DOI: | 10.1055/s-0035-1561300 |
| Popis: | An overview of a convergent, modular route to protected amines, anilines, and related compounds hinging on the degenerate radical addition-transfer of xanthates is presented. Emphasis is placed on the importance of the stabilization of the starting radical by imides and other structures. 1 Introduction 2 The Degenerate Xanthate Transfer Process and Examples of Amine Synthesis 3 Stabilization of Radicals by Imides. Initial Observations and the Radical Aminomethylation of Alkenes 4 More Elaborate Phthalimide-Substituted Xanthates 5 Polyamines and β-Lactams 6 Anilines and Related Derivatives 7 Further Synthetic Variations 8 Outlook and Perspectives |
| Databáze: | OpenAIRE |
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