Tetraphenol-based diphosphite ligands: synthesis, characterization, and application in the rhodium-catalyzed hydroformylation of octenes

Autor:	Dieter Vogt, Dieter Hess, Bart Hamers, Andrea Christiansen, Laura Bini, Robert Franke, Christian Müller, Michèle Janssen
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Ligand Organic Chemistry Substituent Regioselectivity chemistry.chemical_element Biochemistry Aldehyde Catalysis Rhodium chemistry.chemical_compound chemistry Drug Discovery Organic chemistry Hydroformylation
Zdroj:	Tetrahedron Letters, 51(15), 1971-1975. Elsevier
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2010.02.035
Popis:	A new class of diphosphites is described, based on a tetraphenol backbone. Ligands TP1–TP5 were synthesized and fully characterized and their application in the hydroformylation of octenes was investigated. Ligand TP3, bearing a 1-naphthoxy substituent on the phosphorus, shows the highest regioselectivity toward the linear aldehyde.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a401828d4d1d4b9a073911bcac746d4 https://doi.org/10.1016/j.tetlet.2010.02.035 Zobrazit plný text záznamu Full Text from ScienceDirect