Zirconium complexes of diamine-bis(phenolate) ligands: Synthesis, structures, and solution dynamics

Autor:	Stuart R. Dubberley, Nicholas H. Rees, Thierry Toupance, Philip Mountford, Ben R. Tyrrell
Jazyk:	angličtina
Rok vydání:	2016
Předmět:	Inorganic Chemistry chemistry.chemical_classification Crystallography Zirconium chemistry.chemical_compound Chemistry Diamine Organic Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Medicinal chemistry Coordination complex
DOI:	10.1021/om010982w
Popis:	A study was performed on the synthesis, structures and solution dynamics of zirconium complexes of diamine-bis(phenolate) ligands. A series of six- or eight-coordinate derivatives were prepared and crystallographically characterized. It was found that attempts to generate catalytically active systems for the polymerization of ethylene were unsuccessful, although THF-stabilized benzyl cations were identified.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a0649ca2f65f82e85af9da8119614b6 https://doi.org/10.1021/om010982w Zobrazit plný text záznamu