Cinétique de croissance de la face (110) de la paraffine C36H74 en solution
| Autor: | A. Grassi, R. Boistelle, B. Simon |
|---|---|
| Rok vydání: | 1974 |
| Předmět: |
Supersaturation
Classical theory Stereochemistry Chemistry Nucleation Thermodynamics Activation energy Condensed Matter Physics Gibbs free energy Inorganic Chemistry Solvent symbols.namesake chemistry.chemical_compound Impurity Dioctadecylamine Materials Chemistry symbols Physical chemistry Petroleum ether Growth rate Rate of growth |
| Zdroj: | Journal of Crystal Growth. 26:77-89 |
| ISSN: | 0022-0248 |
| DOI: | 10.1016/0022-0248(74)90204-8 |
| Popis: | The rate of growth of (110) faces of the paraffin C36H74 from a solution in petroleum ether has been measured with dioctadecylamine as an impurity, and compared to the growth rate in pure solution. The lowering of the growth rate depends strongly on the concentration of impurity. By comparison to the pure solution, the presence of the impurity has a double effect. First, the activation energy of two dimensional nucleation is enhanced; secondly, the rates of advancement of steps, are also enhanced. At low supersaturation, the first effect is the most effective. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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