Morphology and thermal properties of novel clay-based poly(ethylene 2,5-furandicarboxylate) (PEF) nanocomposites
| Autor: | Volga Niknam, Lucrezia Martino, Jesper Gabriël Van Berkel, Nicolas Sbirrazzuoli, Nathanael Guigo |
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| Přispěvatelé: | Institut de Chimie de Nice, ICN, Institut de Chimie de Nice (ICN), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Côte d'Azur (UCA)-Université Nice Sophia Antipolis (... - 2019) (UNS), COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015-2019) (COMUE UCA), Avantium Chemicals B.V., Groupe d'Etudes des Matériaux Hétérogènes (GEMH), Université de Limoges (UNILIM)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM), Laboratoire de physique de la matière condensée (LPMC), Centre National de la Recherche Scientifique (CNRS)-Université Nice Sophia Antipolis (... - 2019) (UNS) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Materials science Ethylene General Chemical Engineering 02 engineering and technology 010402 general chemistry 01 natural sciences law.invention chemistry.chemical_compound Differential scanning calorimetry law [CHIM] Chemical Sciences [CHIM]Chemical Sciences Thermal stability Crystallization ComputingMilieux_MISCELLANEOUS Nanocomposite General Chemistry [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences Montmorillonite chemistry Chemical engineering Transmission electron microscopy 0210 nano-technology |
| Zdroj: | RSC Advances RSC Advances, Royal Society of Chemistry, 2016 RSC Advances, Royal Society of Chemistry, 2016, 6, pp.59800-59807 |
| ISSN: | 2046-2069 |
| Popis: | International audience; Novel nanocomposites of bio-based poly(ethylene 2,5-furandicarboxylate) (PEF) and organo-modified montmorillonite (OMMT) clays were prepared. Sample morphology was investigated by means of transmission electron microscopy (TEM) and X-ray diffraction (XRD) that revealed a good dispersion of the clay layers in the PEF matrix. Moreover, the effect of clays on the nanocomposites' thermal behavior was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The results show that the presence of clays induces a slight nucleating effect on the PEF crystallization. More remarkably, the clay layers increase significantly the thermal stability of PEF by postponing the initial degradation (+20 °C). |
| Databáze: | OpenAIRE |
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