Third-order nonlinear optical properties of in-backbone substituted conjugated polymers

Autor:	Ulrich Gubler, Simona Concilio, Rainer E. Martin, Peter Günter, F. Diederich, Michael J. Edelmann, Ivan Biaggio, Ch. Bosshard, J. A. Wytko
Rok vydání:	2002
Předmět:	chemistry.chemical_classification Third order nonlinear chemistry.chemical_compound Nonlinear optical Physics and Astronomy (miscellaneous) Polymerization Computational chemistry Chemistry Functional group Hyperpolarizability Molecule Polymer Conjugated system
Zdroj:	Applied Physics Letters. 81:2322-2324
ISSN:	1077-3118 0003-6951
DOI:	10.1063/1.1507834
Popis:	We present an alternative approach to tune the third-order nonlinear optical properties of organic molecules by inserting a functional group into the path of the π-electron conjugation instead of at its ends. We show that this scheme has a beneficial influence on the second-order hyperpolarizability for short molecules, but that in two instances where such molecules were polymerized into longer molecules the overall hyperpolarizability is reduced.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::29f5a11a00e792ab414a527efe2cb988 https://doi.org/10.1063/1.1507834 Zobrazit plný text záznamu