Supported Imidazolylphosphine Catalysts for Highly (E)-Selective Alkene Isomerization

Autor:	Gulin Erdogan, Douglas B. Grotjahn
Rok vydání:	2014
Předmět:	inorganic chemicals chemistry.chemical_classification Alkene organic chemicals Organic Chemistry Biochemistry Catalysis chemistry.chemical_compound chemistry Organic chemistry heterocyclic compounds Fine chemical Physical and Theoretical Chemistry Selectivity Bifunctional Isomerization
Zdroj:	Organic Letters. 16:2818-2821
ISSN:	1523-7052 1523-7060
Popis:	For fine chemical synthesis, immobilized catalysts offer little advantage if they produce a product mixture that must be separated. Selective isomerization of terminal olefins is achieved by heterogenized bifunctional catalysts. Outstanding and consistent (E)-selectivity (>99%) even in cases where (E) and (Z) isomers are of comparable stability, combined with modest catalyst loadings (1 to 2 mol %), set these catalysts apart from previously reported systems. Ease of catalyst removal and high geometric selectivity avoid tedious purifications.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::29e5d9035c3fcccf0a76941d7eda65e6 https://doi.org/10.1021/ol500327k Zobrazit plný text záznamu