| Autor: |
Lisa A. Price, Zöe Jones, Antony Nearchou, Gavin Stenning, Daniel Nye, Asel Sartbaeva |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
AppliedChem; Volume 2; Issue 3; Pages: 149-159 |
| ISSN: |
2673-9623 |
| DOI: |
10.3390/appliedchem2030011 |
| Popis: |
Zeolites with the LTL framework topology are attractive materials for use in optoelectronics, gas adsorption and as chemical reactors. This is due to their unique, one-dimensional (1D) channel systems which are large enough to act as hosts for organic dye molecules and other guest materials. Here, we use high-resolution X-ray diffraction to show the effect of cation exchange on the pore geometry of LTL-type zeolites. The nature of the exchanging cation is shown to influence the free access diameter, volume and water content of the 12-ring (12R) channel systems. As such, cation exchange can be used to tune the molecular sieving and adsorption properties of LTL-type zeolites. This offers new possibilities for these materials in technologically relevant applications. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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