Reticular Growth of Graphene Nanoribbon 2D Covalent Organic Frameworks

Autor: Felix R. Fischer, Wade S. Perkins, Alexander Liebman-Peláez, Chenhui Zhu, Gregory Veber, Cameron Rogers, Jim Ciston, Christian S. Diercks
Rok vydání: 2019
Předmět:
DOI: 10.26434/chemrxiv.9985118
Popis: Synthesis and characterization covalent organic frameworks (COFs) from a small molecule diamine and polydisperse cove type GNRs (c-GNRs) functionalized with aldehydes. The cGNR-COF films were found to contain crystalline regions (>100 nm2) of imine linked GNRs that could be chemically exfoliated into bilayer/trilayers utilizing a sonication protocol with o-dichlorobenzene (o-DCB).
Databáze: OpenAIRE