Delignification of rapeseed straw using innovative chemo-physical pretreatments
Autor: | S. El Kantar, Eugène Vorobiev, Nicolas Brosse, Nabil Grimi, Marwa Brahim, Nadia Boussetta |
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Přispěvatelé: | Transformation Intégrée de la Matière Renouvelable (TIMR), Université de Technologie de Compiègne (UTC), Laboratoire d'Etude et de Recherche sur le Matériau Bois (LERMAB), Université de Lorraine (UL), This work was performed, in partnership with the SAS PIVERT,within the frame of the French Institute for the Energy Transition(Institut pour la Transition Energetique (ITE) P.I.V.E.R.T. (http://www.institut-pivert.com) selected as an Investment for theFuture ('Investissements d’Avenir'). This work was supported, aspart of the Investments for the Future, by the French Governmentunder reference ANR-001-01. |
Rok vydání: | 2016 |
Předmět: |
020209 energy
Alkalinity Lignocellulosic biomass 02 engineering and technology 7. Clean energy [SPI]Engineering Sciences [physics] chemistry.chemical_compound Enzymatic hydrolysis 0202 electrical engineering electronic engineering information engineering Lignin Sugar Waste Management and Disposal ComputingMilieux_MISCELLANEOUS Renewable Energy Sustainability and the Environment business.industry Forestry Straw 021001 nanoscience & nanotechnology Pulp and paper industry 6. Clean water Biotechnology chemistry Biofuel 0210 nano-technology business Agronomy and Crop Science Black liquor |
Zdroj: | Biomass and Bioenergy Biomass and Bioenergy, Elsevier, 2016, 95, pp.92-98. ⟨10.1016/j.biombioe.2016.09.019⟩ |
ISSN: | 0961-9534 1873-2909 |
Popis: | Rapeseed straws are recoverable lignocellulosic biomass for second generation bioethanol production. Therefore, a pretreatment step is recommended in order to increase accessibility of enzymes to sugars. As a pretreatment step in this study, several innovative technologies have been performed in order to investigate their efficiency for delignification and enzymatic hydrolysis purposes: microwaves (MW), high voltage electrical discharges (HVED) and ultrasounds (US). As a key processing parameter, different levels of energy input were studied MW (1832–7328 kJ/kg), US (916–3664 kJ/kg) and HVED (204–814 kJ/kg) corresponding to a treatment duration range of 10–40 min. Treatment temperature (60–90 °C) and medium alkalinity (0.125–0.5 M) impact was also investigated and optimized based on sugar and soluble lignin contents in black liquor, and lignin removal yields. Delignification yields increased from 28.3%, 28.6% and 31.2% for 10 min of treatment to 38.4%, 41.5% and 42.3% for 40 min of treatment, respectively for MW, US and HVED. However, in order to achieve the same efficiency the energy required by HVED is 9 times and 4.5 times less than that required by MW and US respectively. Treatment temperature also revealed to be important as sugars yields increased by 41.6% when temperature increased from 60 °C to 90 °C for HVED and the optimal medium alkalinity was found to be 0.3 M. Finally, better enzymatic hydrolysis yields were obtained and correlated to better delignification performances improving material accessibility. |
Databáze: | OpenAIRE |
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