One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition
| Autor: | Yu Chen, Zong-Quan Wu, Yunsheng Ding, Na Liu, Ying Wang, Xiao-Yue He |
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| Rok vydání: | 2013 |
| Předmět: |
Materials science
One-pot synthesis Metals and Alloys Solid-state Supramolecular chemistry General Chemistry Block (periodic table) Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Monomer chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Copolymer |
| Zdroj: | Chemical Communications. 49:8069 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c3cc43026j |
| Popis: | A series of poly(3-hexylthiophene)-b-poly(hexadecyloxylallene) copolymers has been synthesized in one pot via sequential monomer addition by using Ni(dppp)Cl2 as a single catalyst. The copolymerization has been revealed to proceed by a controlled chain extension mechanism and the block copolymer can self-assemble into a well-defined supramolecular structure in solution and exhibit microphase separation in the solid state. |
| Databáze: | OpenAIRE |
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