A Versatile and Highly Selective Colorimetric Sensor for the Detection of Amines
| Autor: | Craig J. Hawker, Nicolas J. Treat, Zachariah A. Page, Javier Read de Alaniz, Abigail S. Knight, James R. Hemmer, Yvonne J. Diaz |
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| Rok vydání: | 2017 |
| Předmět: |
Absorption spectroscopy
food spoilage One-Step 02 engineering and technology 010402 general chemistry 01 natural sciences Catalysis chemistry.chemical_compound Colorimetric sensor Nucleophile Furan donor-acceptor Stenhouse adducts Detection limit Chemistry colorimetric sensor Organic Chemistry General Chemistry 021001 nanoscience & nanotechnology Combinatorial chemistry Thin-layer chromatography 0104 chemical sciences activated furan Chemical Sciences peptides Naked eye 0210 nano-technology |
| Zdroj: | Diaz, YJ; Page, ZA; Knight, AS; Treat, NJ; Hemmer, JR; Hawker, CJ; et al.(2017). A Versatile and Highly Selective Colorimetric Sensor for the Detection of Amines. CHEMISTRY-A EUROPEAN JOURNAL, 23(15), 3562-3566. doi: 10.1002/chem.201700368. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/2k0121h2 Chemistry (Weinheim an der Bergstrasse, Germany), vol 23, iss 15 |
| ISSN: | 1521-3765 0947-6539 |
| Popis: | The utility of Meldrum's activated furan (MAF) for the colorimetric detection of sub ppm levels of amines in solution, on solid supports, and as vapors is reported. MAF is synthesized in one step from inexpensive and commercially available starting materials and exhibits high selectivity for primary and secondary amines in the presence of competing nucleophiles. The reaction between activated furans and amines results in a distinct color change, discernable by the naked eye. UV/Vis absorption spectroscopy was utilized to monitor reactions in solution and determine detection limits. Additionally, solutions of MAF were useful as stains for thin layer chromatography and for monitoring solid-phase synthesis of peptides and peptidomimetics. Finally, MAF was used to detect volatile amines released from fish samples, demonstrating potential for food spoilage applications. |
| Databáze: | OpenAIRE |
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