Electrically Conductive, Monolithic Metal–Organic Framework–Graphene (MOF@G) Composite Coatings
| Autor: | Rana R. Haikal, Tawheed Hashem, Christof Wöll, Mohamed H. Alkordi, Stefan Heiβler, Franz Koeniger, Julia Rinck, Mohamed H. Hassan, Peter Thissen |
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| Rok vydání: | 2019 |
| Předmět: |
Fabrication
Materials science Graphene Composite number Electrically conductive Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention law General Materials Science Metal-organic framework 0210 nano-technology |
| Zdroj: | ACS Applied Materials & Interfaces. 11:6442-6447 |
| ISSN: | 1944-8252 1944-8244 |
| DOI: | 10.1021/acsami.8b20951 |
| Popis: | We present a novel approach to produce a composite of the HKUST-1 metal-organic framework (MOF) and graphene, which is suited for the fabrication of monolithic coatings of solid substrates. In order to avoid the degradation of graphene electrical properties resulting from chemical functionalization (e.g., oxidation yielding graphene oxide, GO), commercial, nonmodified graphene was utilized. The one-pot synthesis of the moldable composite material allows for a controllable loading of graphene and the tuning of porosity. Potentially, this facile synthesis can be transferred to other MOF systems. The monolithic coatings reported here exhibit high surface areas (1156-1078 m |
| Databáze: | OpenAIRE |
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