Determination of endocrine disrupting chemicals in environmental solid matrices by extraction with a non-ionic surfactant (Tween 80)
| Autor: | Sara Valsecchi, Silvio Capri, S. De Angelis, Luisa Patrolecco, Stefano Polesello |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
Bisphenol A
Lumbriculus variegatus Solid-matrix extraction Polysorbates Sensitivity and Specificity Biochemistry Analytical Chemistry Surface-Active Agents chemistry.chemical_compound Endocrine Glands Sample preparation Solid phase extraction Environmental analysis Detection limit Chromatography biology Chemistry Organic Chemistry Extraction (chemistry) Endocrine disrupters Reproducibility of Results General Medicine Alkylphenols biology.organism_classification Nonylphenol Endocrine disruptor Environmental chemistry Environmental Pollutants |
| Zdroj: | Journal of chromatography info:cnr-pdr/source/autori:PATROLECCO L., CAPRI S., DE ANGELIS S., POLESELLO S., VALSECCHI S./titolo:DETERMINATION OF ENDOCRINE DISRUPTING CHEMICALS IN ENVIRONMENTAL SOLID MATRICES BY EXTRACTION WITH A NON-IONIC SURFACTANT (TWEEN 80)/doi:10.1016%2Fj.chroma.2003.09.050/rivista:Journal of chromatography (Print)/anno:2004/pagina_da:1/pagina_a:7/intervallo_pagine:1–7/volume:1022 |
| ISSN: | 0021-9673 |
| DOI: | 10.1016/j.chroma.2003.09.050 |
| Popis: | A readily applicable method based on extraction by aqueous non-ionic surfactant solutions (Tween 80) and RP-HPLC coupled to fluorescence detection, has been developed for the simultaneous determination of the phenolic endocrine disrupting chemicals (EDCs) nonylphenol (NP), nonylphenol monoethoxylate (NP1EO) and nonylphenol diethoxylate (NP2EO) and bisphenol A (BPA) in environmental solid matrices. Clean up of sample extracts was performed on Si-C18 solid phase extraction (SPE) cartridges. The overall Tween 80 extraction-SPE-RP-HPLC procedure was validated for accuracy and precision by analyzing sediment samples spiked with known amounts of EDCs. Recoveries for NP, NP1EO, NP2EO and BPA and limits of detection are in agreement with conventional extraction methods. The developed methodology was successfully applied to the analysis of target compounds in Italian river sediments, river suspended matter and benthonic macroinvertebrate organisms (oligochaetes Lumbriculus variegatus). Results confirmed that this relatively simple procedure performed satisfactorily in the determination of phenolic EDCs in environmental solid matrices of different complexity and that it can be a suitable alternative method to conventional systems even for routine analyses. |
| Databáze: | OpenAIRE |
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