Highly Selective Adsorption of Perfluorinated Greenhouse Gases by Porous Organic Cages

Autor: Ke Tian, Sven M. Elbert, Xin‐Yue Hu, Tobias Kirschbaum, Wen‐Shan Zhang, Frank Rominger, Rasmus R. Schröder, Michael Mastalerz
Rok vydání: 2022
Předmět:
Zdroj: Advanced Materials. 34:2202290
ISSN: 1521-4095
0935-9648
DOI: 10.1002/adma.202202290
Popis: Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands of times more harmful to the environment than comparable amounts of carbon dioxide. To date, materials that selectively adsorb perfluorocarbons in favor of other less harmful gases have not been reported. Here, a series of porous organic cage compounds with alkyl-, fluoroalkyl-, and partially fluorinated alkyl groups is presented. Their isomorphic crystalline states allow the study of the structure-property relationship between the degree of fluorination of the alkyl chains and the gas sorption properties for PFCs and their selective uptakes in comparison to other, nonfluorinated gases. By this approach, one compound having superior selectivities of PFCs versus N
Databáze: OpenAIRE
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