Synthesis of triazine based dialdehyde Schiff's base – new templates for Molecular Imprinting and study of their structural and photophysical properties
| Autor: | Abhinav B. Tathe, Nagaiyan Sekar, Vikas S. Padalkar |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Chemistry(all) General Chemical Engineering Cyanuric chloride 010402 general chemistry 01 natural sciences Aldehyde lcsh:Chemistry Molecular Imprinting chemistry.chemical_compound Polymer chemistry Moiety Organic chemistry Triazine chemistry.chemical_classification 010405 organic chemistry Chemistry Template General Chemistry Carbon-13 NMR 0104 chemical sciences Photophysics lcsh:QD1-999 Chemical Engineering(all) Proton NMR Schiff's base Molecular imprinting |
| Zdroj: | Arabian Journal of Chemistry, Vol 9, Iss S2, Pp S1793-S1800 (2016) |
| ISSN: | 1878-5352 |
| Popis: | Triazine based dialdehyde (DIPOD) and its Schiff's base derivatives were designed and synthesized from cyanuric chloride as template for Molecular Imprinting. Density functional theory calculation results revealed that the distance between two aldehyde groups is 1.3 nm. Synthesized structurally the rigid template having 1,3,5-triazine as core moiety, has been used as template to introduce two appropriately spaced amino groups for substrate binding on the solid surface of silica. The structures of the synthesized DIPOD and its Schiff's base were characterized by FT-IR, 1 H NMR, 13 C NMR, and UV–Vis spectral analysis. Thermogravimetric analysis showed that the compound has thermal stabilities above 300 °C. |
| Databáze: | OpenAIRE |
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