C6 Diacids from homocitric acid lactone using relay heterogeneous catalysis in water
| Autor: | Stephan N. Steinmann, M. Kit Lau, Roxanne Clément, Indira Thapa, Carine Michel, Elena A. Baranova, Jim Millis, Qingyi Gu, R. Tom Baker, Cathy Staloch Hass, Spyridon Ntais |
|---|---|
| Přispěvatelé: | University of Ottawa [Ottawa], Laboratoire de Chimie - UMR5182 (LC), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation, University of Ottawa, LIA Funcat, Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon)-Institut de Chimie du CNRS (INC) |
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Chemistry Alkene Decarboxylation 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Homocitric acid Heterogeneous catalysis 01 natural sciences Chemical reaction Catalysis 0104 chemical sciences [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry chemistry.chemical_compound Organic chemistry 0210 nano-technology Selectivity Isomerization ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Catalysis Today Catalysis Today, 2019, 319, pp.191-196. ⟨10.1016/j.cattod.2018.08.002⟩ Catalysis Today, Elsevier, 2019, 319, pp.191-196. ⟨10.1016/j.cattod.2018.08.002⟩ |
| ISSN: | 0920-5861 |
| Popis: | Conversion of renewable resources to the chemicals and materials needed for consumer products represents an exciting challenge for catalysis science. Here we discuss our initial progress on synthesizing C6 diacids from the sugar fermentation intermediate α-homo-citric acid lactone using supported heterogeneous catalysts in water. Using high-throughput catalysis testing we have identified several promising catalysts for this process that yield different amounts of the three C6 diacids: adipic, 2-methylglutaric and 2-ethylsuccinic. The process involves a relay of four different chemical reactions: dehydration, alkene isomerization, decarboxylation and alkene hydrogenation. DFT studies have been initiated in order to rationalize the activity and selectivity based on catalyst properties. |
| Databáze: | OpenAIRE |
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