Developing a Thermal- and Coking-Resistant Cobalt–Tungsten Bimetallic Anode Catalyst for Solid Oxide Fuel Cells
| Autor: | Jing-Li Luo, Ning Yan, Jay Pandey, Gadi Rothenberg, Norbert J. Geels, Babak Shalchi Amirkhiz, Bin Hua, Yimin Zeng |
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| Přispěvatelé: | HCSC+ (HIMS, FNWI), Homogeneous and Supramolecular Catalysis (HIMS, FNWI) |
| Rok vydání: | 2016 |
| Předmět: |
Materials science
Hydrogen Metallurgy Oxide chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Direct-ethanol fuel cell 7. Clean energy 01 natural sciences Catalysis Methane 0104 chemical sciences Anode chemistry.chemical_compound chemistry Chemical engineering 0210 nano-technology Cobalt Bimetallic strip |
| Zdroj: | ACS Catalysis, 6(7), 4630-4634. American Chemical Society |
| ISSN: | 2155-5435 |
| DOI: | 10.1021/acscatal.6b01197 |
| Popis: | We report the development of a novel Co–W bimetallic anode catalyst for solid oxide fuel cells (SOFCs) via a facile infiltration-annealing process. Using various microscopic and spectroscopic measurements, we find that the formed intermetallic nanoparticles are highly thermally stable up to 900 °C and show good coking resistance in methane. In particular, a fuel cell fitted with Co3W anode shows comparable activity (relative to Co) in the electro-oxidation of hydrogen and methane at 900 °C without suffering significant degradation during a longevity test. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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