Functionalization of Zirconium‐Based Metal–Organic Layers with Tailored Pore Environments for Heterogeneous Catalysis

Autor:	Hong-Cai Zhou, Shuai Yuan, Jiandong Pang, Jun-Sheng Qin, Christina T. Lollar, Jihong Yu, Guan-Yu Qiao, Dongbin Dang, Heng Rao
Rok vydání:	2020
Předmět:	Anthracene Zirconium Materials science 010405 organic chemistry Ligand chemistry.chemical_element Nanotechnology General Chemistry General Medicine 010402 general chemistry Heterogeneous catalysis 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Transition metal Surface modification Group 2 organometallic chemistry
Zdroj:	Angewandte Chemie. 132:18381-18385
ISSN:	1521-3757 0044-8249
Popis:	Intriguing properties and functions are expected to implant into metal-organic layers (MOLs) to achieve tailored pore environments and multiple functionalities owing to the synergies among multiple components. Herein, we demonstrate a facile one-pot synthetic strategy to incorporate multiple functionalities into stable zirconium MOLs via secondary ligand pillaring. Through the combination of Zr6 -BTB (BTB=benzene-1,3,5-tribenzoate) layers and diverse secondary ligands (including ditopic and tetratopic linkers), 31 MOFs with multi-functionalities were systematically prepared. Notably, a metal-phthalocyanine fragment was successfully incorporated into this Zr-MOL system, giving rise to an ideal platform for the selective oxidation of anthracene. The organic functionalization of two-dimensional MOLs can generate tunable porous structures and environments, which may facilitate the excellent catalytic performance of as-synthesized materials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::286cb761ba2e4ee4655d19a9271e1c68 https://doi.org/10.1002/ange.202007781 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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