Phosphine-catalyzed regioselective Michael addition to allenoates

Autor:	Yixin Lu, Vasudeva Rao Gandi
Rok vydání:	2015
Předmět:	Metals and Alloys Regioselectivity General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Michael reaction Organic chemistry Phosphine
Zdroj:	Chemical Communications. 51:16188-16190
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c5cc06197k
Popis:	The first phosphine catalysed Michael addition of arylcyanoacetates to allenoates has been developed, and the β-selective products with a quaternary center were obtained in excellent yields. This unusual regioselectivity may open new opportunities to access interesting molecular structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2838c54a4de87421922586ff27aef6fd https://doi.org/10.1039/c5cc06197k Zobrazit plný text záznamu